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Which one of the following is most soluble in water?


A) CH3OH
B) CH3CH2CH2OH
C) CH3CH2OH
D) CH3CH2CH2CH2OH
E) CH3CH2CH2CH2CH2OH

F) None of the above
G) All of the above

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A solution is prepared by dissolving 23.7 g of CaCl2 in 375 g of water. The density of the resulting solution is 1.05 g/mL. The concentration of Cl- in this solution is __________ M.


A) 0.214
B) 0.562
C) 1.12
D) 1.20
E) 6.64 × 10-2

F) C) and D)
G) A) and E)

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The concentration of urea (MW = 60.0 g/mol) in a solution prepared by dissolving 16 g of urea in 39g of H2O is __________ molal.


A) 96
B) 6.8
C) 0.68
D) 6.3
E) 0.11

F) D) and E)
G) A) and E)

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A supersaturated solution __________.


A) is one with more than one solute
B) is one that has been heated
C) is one with a higher concentration than the solubility
D) must be in contact with undissolved solid
E) exists only in theory and cannot actually be prepared

F) A) and C)
G) C) and D)

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The mole fraction of urea (MW = 60.0 g/mol) in a solution prepared by dissolving 16 g of urea in 39g of H2O is __________.


A) 0.58
B) 0.37
C) 0.13
D) 0.11
E) 9.1

F) C) and E)
G) A) and E)

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Which one of the following substances is more likely to dissolve in CCl4?


A) CBr4
B) HBr
C) HCl
D) CH3CH2OH
E) NaCl

F) None of the above
G) A) and B)

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For a dilute aqueous solution, a concentration of 1 ppb also corresponds to a concentration of 1 __________ per liter of solution.

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The concentration of nitrate ion in a solution that contains 0.900 M aluminum nitrate is _______ M.


A) 0.900
B) 0.450
C) 0.300
D) 2.70
E) 1.80

F) All of the above
G) D) and E)

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An aqueous solution of a soluble compound (a nonelectrolyte) is prepared by dissolving 33.2 g of the compound in sufficient water to form 250 mL of solution. The solution has an osmotic pressure of 1.2 atm at25°C. What is the molar mass (g/mole) of the compound?


A) 1.0 × 103
B) 2.7 × 103
C) 2.3 × 102
D) 6.8 × 102
E) 28

F) B) and D)
G) C) and D)

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The concentration of urea in a solution prepared by dissolving 16 g of urea in 20 g of H2O is __________% by mass. The molar mass of urea is 60.0 g/mol.


A) 44
B) 80
C) 0.44
D) 0.80
E) 0.48

F) A) and E)
G) A) and D)

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The Henry's law constant for helium gas in water at 30°C is 3.70 × 10-4 M/atm. When the partial pressure of helium above a sample of water is 0.650 atm, the concentration of helium in the water is __________ M.


A) 5.69 × 10-4
B) 1.76 × 103
C) 1.30
D) 2.41 × 10-4
E) 3.70 × 10-4

F) B) and D)
G) B) and E)

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Which of the following liquids will have the lowest freezing point?


A) pure H2O
B) aqueous glucose (0.60 m)
C) aqueous sucrose (0.60 m)
D) aqueous FeI3 (0.24 m)
E) aqueous KF (0.50 m)

F) A) and B)
G) A) and C)

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A solution contains 28% phosphoric acid by mass. This means that __________.


A) 1 mL of this solution contains 28 g of phosphoric acid
B) 1 L of this solution has a mass of 28 g
C) 100 g of this solution contains 28 g of phosphoric acid
D) 1 L of this solution contains 28 mL of phosphoric acid
E) the density of this solution is 2.8 g/mL

F) B) and E)
G) A) and D)

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A solution is prepared by dissolving 23.7 g of CaCl2 in 375 g of water. The density of the resulting solution is 1.05 g/mL. The concentration of CaCl2 in this solution is __________ molar.


A) 0.564
B) 0.571
C) 0.569
D) 0.537
E) 0.214

F) D) and E)
G) None of the above

Correct Answer

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Calculate the molality of a 10.0% (by mass) aqueous solution of hydrochloric acid.


A) 0.274 m
B) 2.74 m
C) 3.05 m
D) 4.33 m
E) The density of the solution is needed to solve the problem.

F) A) and C)
G) A) and B)

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The molarity of urea in a solution prepared by dissolving 16 g of urea (MW = 60.0 g/mol) in 39g of H2O is __________ M. The density of the solution is 1.3 g/mL.


A) 0.11
B) 3.7
C) 6.8
D) 6.3
E) 0.16

F) D) and E)
G) A) and D)

Correct Answer

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The vapor pressure of pure water at 25°C is 23.8 torr. What is the vapor pressure (torr) of water above a solution prepared by dissolving 18.0 g of glucose (a nonelectrolyte, MW = 180.0 g/mol) in 95.0g of water?


A) 24.3
B) 23.4
C) 0.451
D) 0.443
E) 23.8

F) C) and E)
G) B) and E)

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On a clear day at sea level, with a temperature of 25°C, the partial pressure of N2 in air is 0.78 atm and the concentration of nitrogen in water is 5.3 × 10-4 M. When the partial pressure of N2 is __________ atm, the concentration in water is 1.1 × 10-3 M.


A) 0.63
B) 0.78
C) 1.0
D) 2.1
E) 1.6

F) B) and E)
G) A) and B)

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Adding a nonvolatile solute to a solution decreases the vapor pressure of the solution.

A) True
B) False

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Determine the freezing point (°C) of a 0.015 molal aqueous solution of MgSO4. Assume i = 2.0 for MgSO4. The molal freezing-point-depression constant of water is 1.86°C/m.


A) -0.056
B) -0.028
C) -0.17
D) -0.084
E) 0.000

F) C) and D)
G) C) and E)

Correct Answer

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