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The pH of a solution prepared by dissolving 0.350 mol of solid dimethylamine hydrochloride ((CH3) 2NH2Cl) in 1.00 L of 1.10 M dimethylamine ((CH3) 2NH) is ________. The Kb for methylamine is 5.40 × 10-4. (Assume the final volume is 1.00 L.)


A) 1.66
B) 2.77
C) 11.23
D) 11.14
E) none of the above

F) C) and D)
G) A) and B)

Correct Answer

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Consider a solution containing 0.100 M fluoride ions and 0.126 M hydrogen fluoride. The concentration of hydrogen fluoride after addition of 9.00 mL of 0.0100 M HCl to 25.0 mL of this solution is ________ M.


A) 0.0953
B) 0.0900
C) 0.130
D) 0.122
E) 0.00976

F) A) and D)
G) A) and C)

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Consider the following table of Consider the following table of   values.   -Which compound listed below has the smallest molar solubility in water? A) ZnCO<sub>3</sub> B) Cd(OH) <sub>2</sub> C) CdCO<sub>3</sub> D) AgI E) CaF<sub>2</sub> values. Consider the following table of   values.   -Which compound listed below has the smallest molar solubility in water? A) ZnCO<sub>3</sub> B) Cd(OH) <sub>2</sub> C) CdCO<sub>3</sub> D) AgI E) CaF<sub>2</sub> -Which compound listed below has the smallest molar solubility in water?


A) ZnCO3
B) Cd(OH) 2
C) CdCO3
D) AgI
E) CaF2

F) A) and B)
G) A) and C)

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A solution containing which one of the following pairs of substances will be a buffer solution?


A) KI, HI
B) AgBr, HBr
C) CuCl, HCl
D) CsI, HI
E) none of the above

F) B) and D)
G) B) and E)

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A 25.0 mL sample of an HCl solution is titrated with a 0.139 M NaOH solution. The equivalence point is reached with 15.4 mL of base. The concentration of HCl is ________ M.


A) 11.7
B) 0.00214
C) 0.0856
D) 0.267
E) 0.139

F) A) and C)
G) A) and B)

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Calculate the percent ionization of nitrous acid in a solution that is 0.260 M in nitrous acid. The acid dissociation constant of nitrous acid is 4.50 × 10-4.


A) 1.17 × 10-4
B) 0.0450
C) 4.16
D) 0.314
E) 5.78

F) B) and C)
G) D) and E)

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The concentration of iodide ions in a saturated solution of silver iodide is ________ M. The solubility product constant of AgI is 8.3 × 10-17.


A) 3.8 × 10-11
B) 3.0 × 10-10
C) 9.1 × 10-9
D) 3.5 × 10-9
E) 1.4 × 10-8

F) All of the above
G) B) and C)

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Consider a solution containing 0.100 M fluoride ions and 0.126 M hydrogen fluoride. The concentration of fluoride ions after the addition of 9.00 mL of 0.0100 M HCl to 25.0 mL of this solution is ________ M.


A) 0.0735
B) 0.0762
C) 0.0980
D) 0.0709
E) 0.00253

F) A) and D)
G) D) and E)

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Calculate the maximum concentration (in M) of silver ions (Ag+) in a solution that contains 0.025 M of CO32-. The Ksp of Ag2CO3 is 8.1 × 10-12.


A) 1.8 × 10-5
B) 1.4 × 10-6
C) 2.8 × 10-6
D) 3.2 × 10-10
E) 8.1 × 10-12

F) A) and C)
G) A) and B)

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Calculate the percent ionization of formic acid (HCO2H) in a solution that is 0.322 M in formic acid and 0.178 M in sodium formate (NaHCO2) . The Ka of formic acid is 1.77 × 10-4.


A) 35.6
B) 0.1011
C) 10.8
D) 1.03 × 10-3
E) 3.488

F) B) and C)
G) C) and D)

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The solubility of manganese (II) hydroxide (Mn(OH) 2) is 2.2 × 10-5 M. What is the Ksp of Mn(OH) 2?


A) 1.1 × 10-14
B) 4.3 × 10-14
C) 2.1 × 10-14
D) 4.8 × 10-10
E) 2.2 × 10-5

F) B) and E)
G) A) and B)

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Calculate the maximum concentration (in M) of magnesium ions (Mg+2) in a solution that contains 0.025 M of CO32-. The Ksp of MgCO3 is 3.5 × 10-8.


A) 1.8 × 10-5
B) 1.4 × 10-6
C) 2.8 × 10-6
D) 3.2 × 10-10
E) 8.1 × 10-12

F) A) and D)
G) A) and C)

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Calculate the pH of a solution prepared by dissolving 0.250 mol of benzoic acid (C7H5O2H) and 0.150 mol of sodium benzoate (NaC7H5O2) in water sufficient to yield 1.00 L of solution. The Ka of benzoic acid is 6.50 × 10-5.


A) 4.409
B) 3.965
C) 10.035
D) 9.591
E) 5.190

F) B) and E)
G) A) and E)

Correct Answer

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Which of the following could be added to a solution of acetic acid to prepare a buffer?


A) sodium acetate only
B) sodium acetate or sodium hydroxide
C) nitric acid only
D) hydrofluoric acid or nitric acid
E) sodium hydroxide only

F) A) and C)
G) A) and B)

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Which one of the following pairs cannot be mixed together to form a buffer solution?


A) HONH2, HONH3Cl
B) NaCl, HCl
C) RbOH, HF
D) KOH, HNO2
E) H2SO3, KHSO3

F) A) and B)
G) A) and D)

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In which of the following aqueous solutions would you expect AgI to have the highest solubility?


A) pure water
B) 0.050 M BaI2
C) 0.050 M NaI
D) 0.050 M KI
E) 0.010 M AgNO3

F) None of the above
G) D) and E)

Correct Answer

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The concentration of fluoride ions in a saturated solution of barium fluoride is ________ M. The solubility product constant of BaF2 is 1.7 × 10-6.


A) 3.8 × 10-4
B) 3.0 × 10-3
C) 1.5 × 10-2
D) 7.5 × 10-3
E) 1.4 × 10-4

F) C) and D)
G) A) and E)

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What is the solubility (in M) of PbCl2 in a 0.15 M solution of HCl? The Ksp of PbCl2 is 1.6 × 10-5.


A) 2.0 × 10-3
B) 1.1 × 10-4
C) 1.8 × 10-4
D) 7.1 × 10-4
E) 1.6 × 10-5

F) A) and B)
G) A) and E)

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In which of the following aqueous solutions would you expect AgBr to have the lowest solubility?


A) 0.040 M SrBr2
B) pure water
C) 0.040 M NaBr
D) 0.040 M KBr
E) 0.010 M AgNO3

F) D) and E)
G) B) and C)

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What are the principal organs that regulate the pH of the carbonic acid-bicarbonate buffer system in the blood?


A) kidneys, liver
B) lungs, kidneys
C) spleen, liver
D) lungs, skin
E) brain stem, heart

F) A) and D)
G) A) and E)

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