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Write the chemical equation for which the enthalpy of reaction is the lattice energy of KCl(s).

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KCl(s)blured image K

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The Lewis dot symbol for the calcium ion is


A) (The Lewis dot symbol for the calcium ion is A)  (  <sup>2+</sup>)  B) (-Ca-)  C)  (  <sup>2+</sup>)  D) (Ca<sup>2+</sup>)  E) Ca 2+)
B) (-Ca-)
C) (The Lewis dot symbol for the calcium ion is A)  (  <sup>2+</sup>)  B) (-Ca-)  C)  (  <sup>2+</sup>)  D) (Ca<sup>2+</sup>)  E) Ca 2+)
D) (Ca2+)
E) Ca

F) C) and D)
G) B) and C)

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Which one of the following is most likely to be an ionic compound?


A) CaCl2
B) CO2
C) CS2
D) SO2
E) OF2

F) B) and E)
G) B) and C)

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A

Nitrous oxide, N2O, is sometimes called "laughing gas". What is the formal charge on the central nitrogen atom in the best Lewis structure for nitrous oxide? (The atom connectivity is N-N-O.)


A) -2
B) -1
C) 0
D) +1
E) +2

F) B) and E)
G) D) and E)

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Use bond energies to estimate the enthalpy of formation of HBr(g) . BE(H-H) = 436 kJ/mol BE(Br-Br) = 192 kJ/mol BE(H-Br) = 366 kJ/mol


A) +262 kJ/mol
B) -52 kJ/mol
C) -104 kJ/mol
D) +104 kJ/mol
E) +52 kJ/mol

F) All of the above
G) B) and E)

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Assuming the octet rule is obeyed, how many covalent bonds will a nitrogen atom form to give a formal charge of zero?


A) 0
B) 1
C) 2
D) 3
E) 4

F) A) and C)
G) A) and B)

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The number of lone electron pairs in the NO2- ion is ___.


A) 4
B) 5
C) 6
D) 7
E) 8

F) D) and E)
G) None of the above

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The number of resonance structures for the nitrate ion that satisfy the octet rule is


A) 1
B) 2
C) 3
D) 4
E) None of these

F) C) and D)
G) A) and D)

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C

Write a Lewis structure for the chlorite ion, ClO2-, that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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Which one of the following ionic solids would have the largest lattice energy?


A) NaCl
B) NaF
C) CaBr2
D) CsI
E) CaCl2

F) None of the above
G) A) and B)

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Which one of the following molecules has an atom with an expanded octet?


A) HCl
B) AsCl5
C) ICl
D) NCl3
E) Cl2

F) B) and C)
G) A) and C)

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Which of the following Lewis structures is incorrect?


A) Which of the following Lewis structures is incorrect? A)    B)    C)    D)    E)
B) Which of the following Lewis structures is incorrect? A)    B)    C)    D)    E)
C) Which of the following Lewis structures is incorrect? A)    B)    C)    D)    E)
D) Which of the following Lewis structures is incorrect? A)    B)    C)    D)    E)
E) Which of the following Lewis structures is incorrect? A)    B)    C)    D)    E)

F) A) and E)
G) A) and D)

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The electron dot formula for O2 shows


A) a single covalent bond
B) a double covalent bond
C) an ionic bond
D) a total of 8 x 2 = 16 electron dots
E) a total of 32 electron dots

F) A) and D)
G) C) and D)

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Write a Lewis structure for the chlorate ion, ClO3-, that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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Which one of the following is most likely to be a covalent compound?


A) CsOH
B) NF3
C) Sr(NO3) 2
D) CaO
E) LiF

F) All of the above
G) A) and B)

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Carbonic acid, H2CO3, is a weak acid that contributes to the taste and produces the carbon dioxide bubbles in all carbonated beverages.Write a Lewis structure for H2CO3,

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11ea7cc5_018d_72ce_a2ab_876865e601f5_TB3245_00

Calculate the energy change for the reaction K(g) + Br(g) β†’\rarr K+(g) + Br- (g) Given the following ionization energy (IE) and electron affinity (EA) values  Calculate the energy change for the reaction K(g) + Br(g)  \rarr  K<sup>+</sup>(g) + Br<sup>-</sup> (g)  Given the following ionization energy (IE) and electron affinity (EA) values   A) -1,092 kJ/mol B) -95 kJ/mol C) 95 kJ/mol D) 1,092 kJ/mol E) 1,187 kJ/mol


A) -1,092 kJ/mol
B) -95 kJ/mol
C) 95 kJ/mol
D) 1,092 kJ/mol
E) 1,187 kJ/mol

F) C) and D)
G) A) and C)

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Write a Lewis structure for the phosphate ion, PO43-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for PO43- that obey the octet rule.

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blured image Total number of res...

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Which of the following is a useful guideline for the application of formal charges in neutral molecules?


A) A Lewis structure in which there are no formal charges is preferred.
B) Lewis structures with large formal charges are preferred.
C) The preferred Lewis structure is one in which positive formal charges are on the most electronegative atoms.

D) A) and B)
E) A) and C)

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Write a Lewis structure for SO3 that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s).

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