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Which of the following is not true of molecular orbitals?


A) The number of molecular orbitals formed is always equal to the number of atomic orbitals combined.
B) A molecular orbital can accommodate up to two electrons.
C) When electrons are added to orbitals of the same energy, the most stable arrangement is predicted by Hund's rule.
D) Low-energy molecular orbitals fill before high-energy molecular orbitals fill.
E) For any substance, the number of electrons in molecular orbitals is equal to the sum of all the valence electrons on the bonding atoms.

F) A) and B)
G) C) and D)

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The F -Cl -F bond angles in ClF3 are expected to be approximately


A) 90° only.
B) 109.5° only.
C) 120° only.
D) 180° only.
E) 90° and 180°.

F) A) and B)
G) B) and E)

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The geometry of the ClF3 molecule is best described as:


A) distorted tetrahedron
B) trigonal planar
C) tetrahedral
D) T-shaped
E) trigonal pyramidal

F) A) and B)
G) D) and E)

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What is the bond order of CO+


A) 1
B) 1.5
C) 2
D) 2.5
E) 3

F) None of the above
G) A) and E)

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The bond angles in SCl2 are expected to be


A) a little less than 109.5°.
B) 109.5°.
C) a little more than 109.5°.
D) 120°.
E) 180°.

F) A) and D)
G) B) and D)

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Indicate the type of hybrid orbitals used by the central atom in SF6.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and D)
G) A) and C)

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What bond angles are predicted by VSEPR theory for the F -P -F bonds in PF5?

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Valence Bond Theory alone can be used to determine that O2 is paramagnetic.

A) True
B) False

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Ibuprofen is used as an analgesic for the relief of pain, and also to help reduce fever.What is the hybridization state of carbon indicated by the arrow in the structure of ibuprofen shown below? Ibuprofen is used as an analgesic for the relief of pain, and also to help reduce fever.What is the hybridization state of carbon indicated by the arrow in the structure of ibuprofen shown below?   A) sp B) sp<sup>2</sup> C) sp<sup>3</sup> D) sp<sup>3</sup>d E) sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and B)
G) None of the above

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Give the number of lone pairs around the central atom and the geometry of the ion ClO3-.


A) 0 lone pairs, trigonal
B) 1 lone pair, bent
C) 1 lone pair, trigonal pyramidal
D) 2 lone pairs, T-shaped
E) 2 lone pairs, trigonal

F) A) and C)
G) A) and B)

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More energy is required to break a bond with an order of 3/2 than is required to break a bond of order 2.

A) True
B) False

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Indicate the number of π\pi -bonds in C2H6.

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N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents.What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below? N,N-diethyl-m-tolumide (DEET) is the active ingredient in many mosquito repellents.What is the hybridization state of carbon indicated by the arrow in the structure of DEET shown below?   A) sp B) sp<sup>2</sup> C) sp<sup>3</sup> D) sp<sup>3</sup>d E) sp<sup>3</sup>d<sup>2</sup>


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and B)
G) A) and C)

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Which of the following molecules has polar bonds but is a nonpolar molecule?


A) PCl3
B) NCl3
C) BF3
D) HF
E) OCl2

F) A) and E)
G) A) and D)

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Which of the following correctly lists species in order of increasing bond order?


A) C2 < Li2 < Be2 < N2
B) Be2 < Li2 < C2 < N2
C) N2 < Be2 < Li2 < C2
D) N2 < C2 < Li2 < Be2
E) Be2 < C2 < N2 < Li2

F) None of the above
G) A) and E)

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The bond angles in ICl2- are expected to be


A) a little less than 109.5°.
B) 109.5°.
C) a little more than 109.5°.
D) 120°.
E) 180°.

F) C) and E)
G) B) and D)

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Use VSEPR theory to predict the molecular geometry of SF4 (sulfur tetrafluoride).

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distorted ...

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Which one of the following molecules has a non-zero dipole moment?


A) BeCl2
B) Br2
C) BF3
D) IBr
E) CO2

F) D) and E)
G) B) and D)

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Which of the following correctly lists species in order of increasing bond length?


A) O2 < O2+ < O2-
B) O2- < O2 < O2+
C) O2+ < O2 < O2-
D) O2- < O2+ < O2
E) O2+ < O2- < O2

F) All of the above
G) B) and D)

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Use VSEPR theory to predict the molecular geometry of CO32-.

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