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Which of the following statements is generally TRUE?


A) The solubility of a solid is not dependent on either temperature or pressure.
B) The solubility of a solid is highly dependent on pressure.
C) The solubility of a solid is highly dependent on both pressure and temperature.
D) The solubility of a solid is highly dependent on temperature.
E) None of the above.

F) A) and D)
G) A) and E)

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A 4.55 L sample of water contains 0.115 g of sodium ions.Determine the concentration of sodium ions in ppm if the density of the solution is 1.00 g/mL.


A) 52.3 ppm
B) 13.2 ppm
C) 12.7 ppm
D) 25.3 ppm
E) 36.5 ppm

F) A) and B)
G) A) and C)

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Calculate the freezing point of a solution of 40.0 g methyl salicylate,C7H6O2,dissolved in 800.g of benzene,C6H6.Kf for benzene is 5.10°C/m and the freezing point is 5.50°C for benzene.


A) - 2.09°C
B) 2.09°C
C) 3.41°C
D) 7.59°C

E) C) and D)
F) B) and D)

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Choose the aqueous solution below with the highest freezing point.These are all solutions of nonvolatile solutes and you should assume ideal van't Hoff factors where applicable.


A) 0.200 m Mg(ClO4) 2
B) 0.200 m Na3PO3
C) 0.200 m HOCH2CH2OH
D) 0.200 m Ba(NO3) 2
E) These all have the same freezing point.

F) B) and C)
G) A) and C)

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What is the freezing point of a solution of 7.15 g MgCl2 in 100 g of water? Kf for water is1.86°C/m.


A) -0.140°C
B) - 1.40°C
C) - 2.80°C
D) - 4.18°C

E) All of the above
F) B) and C)

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A solution of LiCl in water is 20.0 wt% LiCl.What is the mole fraction of LiCl?


A) 0.0960
B) 0.106
C) 0.472
D) 4.44

E) None of the above
F) All of the above

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A solution is prepared by dissolving 76.3 g NaI in 545 g of water.Determine the mole fraction of NaI if the final volume of the solution is 576 mL.


A) 6.04 × 10-3
B) 1.65 × 10-2
C) 1.40 × 10-3
D) 1.32 × 10-2
E) 8.84 × 10-2

F) D) and E)
G) C) and D)

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How many moles of KF are contained in 347 g of water in a 0.175 m KF solution?


A) 1.65 × 10-2 mol KF
B) 5.04 × 10-2 mol KF
C) 6.07 × 10-2 mol KF
D) 3.22 × 10-2 mol KF
E) 1.98 × 10-2 mol KF

F) C) and E)
G) B) and E)

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Determine the solubility of N2 in water exposed to air at 25°C if the atmospheric pressure is 2.0 atm.Assume that the mole fraction of nitrogen is 0.78 in air and the Henry's law constant for nitrogen in water at this temperature is 6.1 × 10-4 M/atm.


A) 1.6 × 10-4 M
B) 6.4 × 10-4 M
C) 9.5 × 10-4 M
D) 1.1 × 10-4 M
E) 1.2 × 10-4 M

F) A) and B)
G) A) and C)

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Explain why the van't Hoff factor for MgCl2 is less than it's predicted value.

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The hydrated Mg2⁺ and Cl⁻ ions ...

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Identify the compound whose solubility decreases with increasing temperature.


A) Na2SO4
B) K2Cr2O7
C) NaNO3
D) KClO3
E) CaCl2

F) A) and D)
G) A) and C)

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Choose the statement below that is TRUE.


A) A solution will form between two substances if the solute-solvent interactions are of comparable strength to the solute-solute and solvent-solvent interactions.
B) A solution will form between two substances if the solute-solvent interactions are small enough to be overcome by the solute-solute and solvent-solvent interactions.
C) A solution will form between two substances if the solute-solute interactions are strong enough to overcome the solvent-solvent interactions.
D) A solution will form between two substances only if the solvent-solvent interactions are weak enough to overcome the solute-solvent interactions.
E) None of the above are true.

F) A) and B)
G) C) and D)

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Calculate the molality of a solution formed by dissolving 34.8 g of LiI in 500.0 mL of water.


A) 0.254 m
B) 0.130 m
C) 0.696 m
D) 0.260 m
E) 0.520 m

F) B) and E)
G) C) and D)

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Calculate the mole fraction of the total ions in an aqueous solution prepared by dissolving 0.400 moles of Ca F2 in 850.0 g of water.


A) 0.00841
B) 0.0270
C) 0.00900
D) 0.0248
E) 0.0167

F) A) and D)
G) A) and B)

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Match the following.

Premises
0.020 m NH4Cl
0.0050 m CO2
0.050 m NaCl
0.010 m Al(NO3)3
0.050 m C6H12O6 (aqueous)
Responses
largest van't Hoff factor
solution that is most strongly dependent upon pressure
highest boiling point
solution of ionic compound with highest freezing point
solution with ΔTb = 0.026°C

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0.020 m NH4Cl
0.0050 m CO2
0.050 m NaCl
0.010 m Al(NO3)3
0.050 m C6H12O6 (aqueous)

A solution is 0.0480 m LiF.What is the molarity of the solution if the density is 1.10 g/mL?


A) 0.0441 M
B) 0.0480 M
C) 0.0436 M
D) 0.0528 M
E) 0.0417 M

F) None of the above
G) B) and C)

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What is the expected freezing point of a 0.50 m solution of Li2SO4 in water? Kf for water is 1.86°C/m.


A) -0.93°C
B) -1.9°C
C) -2.8°C
D) -6.5°C

E) None of the above
F) B) and C)

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A solution is prepared by dissolving 1.928 g of KNO3 into enough water to make 651 mL.What is the molarity of the solution?


A) 0.159 M
B) 0.381 M
C) 0.0293 M
D) 2.48 M
E) 0.0832 M

F) A) and E)
G) A) and D)

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The vapor pressure of a solution is always that of the pure solvent


A) equal to
B) twice
C) one half
D) higher than
E) lower than

F) B) and D)
G) A) and E)

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Choose the aqueous solution below with the lowest freezing point.These are all solutions of nonvolatile solutes and you should assume ideal van't Hoff factors where applicable.


A) 0.075 m Li Cl
B) 0.075 m (NH4) 3PO4
C) 0.075 m NaBrO4
D) 0.075 m KCN
E) 0.075 m KNO2

F) A) and D)
G) B) and E)

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