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What is the molecular geometry of ClF4 -?


A) seesaw
B) square planar
C) square pyramidal
D) tetrahedral

E) All of the above
F) A) and B)

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Draw a molecular orbital diagram and use it to determine which of the following is most stable.


A) C22
B) N22
C) B2
D) C22
E) B22

F) None of the above
G) C) and E)

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Determine the electron geometry (eg) and molecular geometry (mg) of CO32⁻.


A) eg = tetrahedral, mg = tetrahedral
B) eg = tetrahedral, mg = trigonal pyramidal
C) eg = trigonal planar, mg = bent
D) eg = trigonal planar, mg = trigonal planar
E) eg = tetrahedral, mg = trigonal planar

F) A) and B)
G) A) and C)

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Determine the electron geometry (eg) and molecular geometry (mg) of PF5.


A) eg = trigonal bipyramidal, mg = trigonal bipyramidal
B) eg = octahedral, mg = octahedral
C) eg = trigonal bipyramidal, mg = tetrahedral
D) eg = tetrahedral, mg = trigonal pyramidal
E) eg = trigonal planar, mg = octahedral

F) All of the above
G) B) and D)

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Using the VSEPR model, the molecular geometry of the central atom in CF4 is ________.


A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal

F) B) and C)
G) A) and D)

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A molecule containing a central atom with sp3d hybridization has a(n) ________ electron geometry.


A) tetrahedral
B) linear
C) octahedral
D) trigonal planar
E) trigonal bipyramidal

F) A) and E)
G) C) and D)

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Is it possible for a molecule to be nonpolar even though it contains polar bonds? Explain your answer and give an example.

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Yes. The polarity of a molecule depends ...

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How many of the following molecules have sp2 hybridization on the central atom? HCN SO2 OCl2 XeCl2


A) 4
B) 3
C) 2
D) 1
E) 0

F) A) and D)
G) B) and C)

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Determine the electron geometry for the molecule BrF3.


A) Linear
B) Trigonal planar
C) Tetrahedral
D) Trigonal bipyramidal
E) Octahedral

F) A) and E)
G) A) and D)

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Determine the molecular geometry for the molecule PCl5.


A) Linear
B) Seesaw
C) Square pyramidal
D) Trigonal bipyramidal
E) Square planar

F) B) and C)
G) A) and B)

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Draw the Lewis structure for SO2-3. What is the hybridization on the S atom?


A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2

F) A) and C)
G) A) and E)

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Choose the compound below that contains at least one polar covalent bond but is nonpolar.


A) GeH2Br2
B) SCl2
C) AsCl5
D) CF2Cl2
E) All of the above are nonpolar and contain a polar covalent bond.

F) All of the above
G) A) and B)

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Determine the molecular geometry for the molecule PF3.


A) Trigonal pyramidal
B) Trigonal planar
C) Tetrahedral
D) T-shaped
E) Bent

F) A) and B)
G) None of the above

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A molecule or ion with three electrons in bonding orbitals and two electrons in an antibonding orbital has a bond order of:


A) 0.5
B) 1
C) 1.5
D) 2
E) 3

F) B) and E)
G) A) and E)

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What is the molecular geometry of TeCl4?


A) seesaw
B) square planar
C) square pyramidal
D) tetrahedral

E) C) and D)
F) A) and B)

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Match the following. -sp3d


A) tetrahedral
B) nonpolar, but contains a polar covalent bond
C) sp hybridized central atom
D) trigonal bipyramidal
E) trigonal planar
F) polar
G) linear
H) seesaw molecular geometry
I) octahedral
J) octahedral electron geometry
K) polar, but contains no polar bonds
L) sp2 hybridized central atom

M) A) and F)
N) E) and J)

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Determine the electron geometry (eg) and molecular geometry (mg) of SiF4.


A) eg = tetrahedral, mg = trigonal pyramidal
B) eg = octahedral, mg = square planar
C) eg = trigonal bipyramidal, mg = trigonal pyramidal
D) eg = tetrahedral, mg = bent
E) eg = tetrahedral, mg = tetrahedral

F) A) and D)
G) C) and D)

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What are the F-Po-F bond angles in PoF6?


A) 60°
B) 90°
C) 109.5°
D) 120°

E) None of the above
F) A) and D)

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Using the VSEPR model, the electron-domain geometry of the central atom in BrF4- is ________.


A) linear
B) trigonal planar
C) tetrahedral
D) trigonal bipyramidal
E) octahedral

F) C) and D)
G) A) and D)

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Place the following in order of decreasing X-A-X bond angle, where A represents the central atom and X represents the outer atoms in each molecule. N2O NCl3 NO2


A) NCl3 > NO2⁻ > N2O
B) NO2⁻ > N2O > NCl3
C) N2O > NO2⁻ > NCl3
D) NCl3 > N2O > NO2
E) N2O > NCl3 > NO2

F) A) and D)
G) C) and E)

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