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How many lone pairs of electrons are on the group of atoms that characterize organic acids?


A) 6
B) 4
C) 3
D) 2
E) 1

F) A) and C)
G) C) and D)

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For the HCl molecule, the dipole moment is calculated from q × r. Calculations show that q equals 0.17 electronic charge units. This means the hydrogen carries a charge of ________ and the chlorine a charge of ________.

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Draw the Lewis structure for ClSO3, optimized for formal charge considerations, showing all resonance structures.

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Based on the "best"Lewis structure after applying formal charge considerations, how many non-bonding valence electrons are around the nitrogen atom in the nitrate ion?


A) 0
B) 2
C) 4
D) 6
E) 8

F) A) and D)
G) A) and C)

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Draw a Lewis structure for NH4+. Based on this Lewis structure, the calculated value for the formal charge on the nitrogen atom is


A) 0.
B) 4+.
C) 1+.
D) 1-.
E) 4- .

F) B) and E)
G) B) and C)

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The octet rule is generally followed for cations of elements located where on the periodic table?


A) post transition metals and transition metals
B) Group IA and Group IIA metals
C) Group IVA elements
D) lanthanide elements
E) actinide elements

F) B) and D)
G) A) and E)

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Based on the "best"Lewis structure after applying formal charge considerations, how many non-bonding valence electrons are around the carbon atom in the CO molecule?


A) 0
B) 2
C) 4
D) 6
E) 8

F) None of the above
G) C) and E)

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Draw the Lewis structure for H2SeO4. If the valence shells are filled to the usual limit (a maximum of 8) , what is the formal charge on the Se? Hint: Do not forget about double or triple bonds potentially being in the Lewis structure.


A) 2-
B) 1-
C) 0
D) 1+
E) 2+

F) C) and D)
G) C) and E)

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The Lewis symbol for the nitrogen atom has ________ valence electrons. The number of covalent bonds that nitrogen usually forms to complete its valence shell and obey the octet rule is ________.


A) 5, 1
B) 5, 2
C) 3, 4
D) 5, 3
E) 5, 4

F) D) and E)
G) C) and E)

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The fluorophosphonate ion, FPO32−, has a structure similar to that of the orthophosphate ion, the difference being that one of the oxygen atoms has been replaced by a fluorine atom. Draw the Lewis structure for this ion, optimized for formal charge considerations, showing all resonance structures.

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Draw the Lewis structure for the F2CO molecule. Based on this structure, how many polar bonds and non-polar bonds are present? Hint: Do not forget about double or triple bonds potentially being in the Lewis structure.


A) 3 polar bonds and no non-polar bonds
B) 2 polar bonds and 1 non-polar bond
C) 1 polar bond and 2 non-polar bonds
D) no polar bonds and 3 non-polar bonds
E) 2 polar bonds and 2 non-polar bonds

F) A) and B)
G) A) and E)

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The F-O bond is more polar than the H-O bond.

A) True
B) False

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Draw the Lewis structure for the sulfur dioxide molecule. When formal charge considerations are fully considered and adjustments made, if necessary, how many resonance structures, if any, can be drawn?

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The Born-Haber cycle, which is an enthalpy diagram that can be used to calculate the lattice energy of an ionic compound, has how many endothermic steps?

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The formal charge on the nitrogen atom in the nitrate ion (NO3-) is


A) 3-
B) 0
C) 1+
D) 3+
E) 5+

F) C) and E)
G) A) and E)

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The Lewis symbol for the selenium atom shows ________ valence shell electrons. The number of covalent bonds that selenium normally forms to complete its valence shell and obey the octet rule is ________.

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Draw a Lewis structure for CH3NO2. Based on the Lewis structure, what is the formal charge on the nitrogen atom for the most favorable structure? Hint: Minimize formal charge to ensure you have the most stable or "best"Lewis structure.


A) -2
B) -1
C) 0
D) +1
E) +2

F) A) and E)
G) All of the above

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When electrons are removed from a given shell to form a cation, they come from the highest energy occupied subshell first before any are removed from a lower-energy subshell.

A) True
B) False

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Based on the Δ\Deltaf data given, which compound is the most stable?


A) N2O4(g) , +9.7 kJ/mol
B) H2S(g) , -20.6 kJ/mol
C) N2H4(g) , +94.5 kJ/mol
D) PH3(g) , +5.4 kJ/mol
E) NH3(g) , -46.4 kJ/mol

F) None of the above
G) All of the above

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Based on electronegativity considerations, which species should be the strongest oxidizing agent?


A) Xe
B) As
C) Br2
D) I2
E) Sb

F) B) and D)
G) All of the above

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