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At 60 °C the value of Kw is 9.5 × 10-14. Considering this, what is the pOH of pure water this temperature?


A) 6.02
B) 6.51
C) 7.00
D) 7.49
E) 9.50

F) A) and D)
G) A) and C)

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Calculate the pH of a 0.14 M HNO2 solution that is 5.7% ionized.


A) 11.90
B) 0.85
C) 1.70
D) 13.10
E) 2.10

F) B) and C)
G) A) and B)

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The pH at the equivalence point of the titration of ammonia solution by hydrochloric acid solution is


A) < 2.00.
B) 4.00 < pH < 7.00.
C) 7.00.
D) 7.00 < pH < 11.00.
E) > 11.0.

F) B) and C)
G) B) and D)

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Hydrazine is a base, and the value of its constant, Kb, is 1.70 × 10-6. What is the value of pKb for this base?


A) +4.30
B) +5.77
C) -5.77
D) +8.23
E) -8.23

F) A) and B)
G) B) and D)

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A mixture contains 400.0 mL of 1.00 M NH3(aq), whose pKb is = 4.76, and 400.0 mL of 1.00 M NH4Cl(aq). 200.0 mL of 0.0500 M HCl(aq)were added to the mixture. What is the pH of the buffer before addition of the acid and after addition of the acid? Hint: Calculate the pH of this buffer solution once before the acid and base are neutralized, and again once after. Organizing your information will be just as important as applying chemistry concepts.

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An aqueous solution of Ca(NO3)2 would result in a solution that would be ________.

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Given 0.01 M solutions of each of the following acids, which solution would have the lowest pH?


A) Hypoiodous acid (HOI) , Ka = 2.3 × 10-11
B) Hypobromous acid (HOBr) , Ka = 2.5 × 10-9
C) Lactic acid (HC3H5O3) , Ka = 1.3 × 10-4
D) Chlorous acid (HClO2) , Ka = 1.1 × 10-2
E) Boric acid (H3BO3) , Ka = 5.9 × 10-10

F) B) and E)
G) A) and E)

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A 0.200 M solution of an acid has a pH = 1.000. What is the value of the ionization constant, Ka, for this acid?


A) 0.200
B) 0.0400
C) 1.00 × 10-3
D) 1.00
E) 1.00 × 10-1

F) A) and E)
G) A) and D)

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Given the following: 0.20 M NaOH(aq) 0.20 M HCl(aq) A mixture is made using 50.0 mL of the HCl and 50.0 mL of the NaOH.What is its pH at 25.0 °C?


A) 3.62
B) 4.57
C) 6.30
D) 7.00
E) 9.46

F) A) and B)
G) A) and C)

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The pKa for HC2H3O2(aq)is 4.76. What should be the pH of a mixture containing 100.0 mL of0.300 M NaC2H3O2(aq), 100 mL of 0.300 M HC2H3O2(aq), and 100 mL of 0.100 M NaOH?Hint: After neutralizing the acid and base, treat this solution as a buffer. Organizing your information will be just as important as applying chemistry concepts.

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Solutions of chlorine bleach contain the hypochlorite ion, OCl, which is a weakbase. Write the appropriate equation for Kb for this anion.

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The equation for the...

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What is the pH of a 0.210 M solution of protonated pyridine, C5H5NH+?The Kb of pyridine is 1.5 × 10−9.Hint: Use Ka for weak acids and Kb for weak bases.

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Pyridine is a weak base; the protonated ...

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A 0.075 M solution of a weak base in water has a pH = 11.21 at 25°C. Calculate the value of Kb for this base.


A) 1.6 × 10-3
B) 5.1 × 10-22
C) 2.2 × 10-2
D) 3.6 × 10-5
E) 6.2 × 10-12

F) All of the above
G) B) and C)

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50.00 mL of 0.10 M HNO2 (nitrous acid, Ka = 4.5 × 10−4)is titrated with a 0.10 M KOH solution. What would be the pH of the solution after 25.00 mL of the KOH solution is added?Hint: After the partial neutralization, treat the solution as a buffer.

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A 0.350 M solution of an unknown base has a pH = 10.3. What is the value of the ionization constant, Kb, for the unknown base?

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Calculate the pH of a mixture made by adding 50.0 mL of 0.20 M HCl(aq) to 150.0 mL of water at 25.0 °C.


A) 0.70
B) 1.00
C) 1.18
D) 1.30
E) 13.00

F) None of the above
G) B) and C)

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Formic acid, HCO2H, has an ionization constant with the value: Ka = 1.76 × 10?4. Calculate the value of pKb for the formate ion, CO2H-, the conjugate base of formic acid.


A) 3.75
B) 5.35
C) 8.65
D) 10.25
E) 12.24

F) D) and E)
G) C) and D)

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The pH of a 0.0085 M HA (weak acid)solution is 4.70. What is the percent ionization of the acid in this solution?

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A scientist is testing a new cleaning chemical and measures the pH of the cleaner to be 10.70. What is the [H3O+] for this cleaner?


A) 2.0 × 10-11 M
B) 10.7 M
C) 9.3 × 10-10 M
D) 1.03 M
E) 5.0 × 10-10 M

F) B) and D)
G) A) and B)

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What is the pH of a 1.00 molar solution of NaC2H3O2(aq) ?The Ka for acetic acid (HC2H3O2) is 1.8 × 10-5.


A) 2.37
B) 4.63
C) 4.75
D) 9.37
E) 11.63

F) A) and B)
G) None of the above

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