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According to the kinetic theory of gases, in a collision between two molecules the kinetic energy of one molecule will decrease by the same amount that the kinetic energy of the other one increases.

A) True
B) False

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According to the postulates of kinetic-molecular theory, the average kinetic energy of gas molecules is proportional to the absolute temperature.

A) True
B) False

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Helium gas is being pumped into a rigid container at a constant temperature. As a result, the pressure of helium in the container is increasing. Select the one correct statement below.


A) As the pressure increases, helium atoms move faster, on average.
B) As the pressure increases, helium atoms move more slowly, on average.
C) As the pressure increases, the volume of the container must decrease.
D) As the pressure increases, helium atoms stay closer to the wall of the container, on average.
E) As the pressure increases, there are more collisions of helium atoms with the container wall.

F) None of the above
G) B) and E)

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For a pure gas sample, the average kinetic energy is also the most probable kinetic energy.

A) True
B) False

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Small quantities of hydrogen can be prepared by the addition of hydrochloric acid to zinc. A sample of 195 mL of hydrogen was collected over water at 25°C and 753 torr. What mass of hydrogen was collected? (Pwater = 24 torr at 25°C)


A) 0.00765 g
B) 0.0154 g
C) 0.0159 g
D) 0.0164 g
E) 0.159 g

F) A) and E)
G) B) and C)

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The rate of diffusion of a gas is inversely proportional to its molar mass.

A) True
B) False

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"The pressure of an ideal gas is directly proportional to its absolute temperature at constant volume and number of moles" is a statement of __________ Law.


A) Charles's
B) Boyle's
C) Amontons's
D) Avogadro's
E) Gay-Lussac's

F) B) and D)
G) C) and E)

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A gas consists of 85.7 percent carbon and 14.3 percent hydrogen, by weight. A sample of this gas weighing 0.673 g occupies 729 mL at a pressure of 720.0 mmHg and a temperature of 77°C. Calculate its empirical and molecular formulas.


A) CH, C 2H 2
B) CH 2, C 2H 4
C) CH 2, C 3H 6
D) CH 3, C 2H 6
E) CH 4, CH 4

F) A) and D)
G) A) and C)

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The ozone layer is important because


A) ozone absorbs low energy radiation which warms the troposphere.
B) ozone purifies the atmosphere by reacting with excess fluorocarbons.
C) ozone absorbs ultraviolet radiation.
D) ozone reflects high energy radiation such as X-rays and gamma rays.
E) humans need to breathe air containing some ozone.

F) B) and D)
G) A) and B)

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A ballerina weighs 103 lbs and is up on her toes with only 10.0 cm2 of her slippers in contact with the floor. What pressure is she exerting on the floor?


A) 4.59 × 10 5 Pa
B) 4.59 × 10 3 Pa
C) 4.59 × 10 1 Pa
D) 4.59 × 10 1 Pa
E) 4.59 × 10 3 Pa

F) A) and E)
G) A) and C)

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"The rate of effusion of a gas is inversely proportional to the square root of its molar mass" is a statement of __________ Law.


A) Charles's
B) Graham's
C) Dalton's
D) Avogadro's
E) Boyle's

F) A) and E)
G) B) and C)

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At very high pressures (~ 1000 atm) , the measured pressure exerted by real gases is greater than that predicted by the ideal gas equation. This is mainly because


A) such high pressures cannot be accurately measured.
B) real gases will condense to form liquids at 1000 atm pressure.
C) gas phase collisions prevent molecules from colliding with the walls of the container.
D) of attractive intermolecular forces between gas molecules.
E) the volume occupied by the gas molecules themselves becomes significant.

F) B) and E)
G) A) and B)

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Which of the following gases effuses most rapidly?


A) Nitrogen
B) Oxygen
C) Hydrogen chloride
D) Ammonia
E) Carbon monoxide

F) None of the above
G) A) and B)

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A sample of nitrogen gas at 298 K and 745 torr has a volume of 37.42 L. What volume will it occupy if the pressure is increased to 894 torr at constant temperature?


A) 22.3 L
B) 31.2 L
C) 44.9 L
D) 112 L
E) 380 L

F) A) and D)
G) A) and C)

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Mineral oil can be used in place of mercury in manometers when small pressure changes are to be measured. What is the pressure of an oxygen sample in mm of mineral oil if its pressure is 28.5 mm Hg? (d of mineral oil = 0.88 g/mL; d of Hg = 13.5 g/mL)


A) 1.9 mm mineral oil
B) 15 mm mineral oil
C) 32 mm mineral oil
D) 380 mm mineral oil
E) 440 mm mineral oil

F) A) and B)
G) A) and C)

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Calculate the pressure of a helium sample at −207.3°C and 768 mL if it exerts a pressure of 175 kPa at 25.0°C and 925 mL.


A) 32.1 kPa
B) 46.6 kPa
C) 657 kPa
D) 953 kPa
E) Not possible, since the pressure would have to be negative

F) A) and B)
G) A) and C)

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Hydrochloric acid is prepared by bubbling hydrogen chloride gas through water. What is the concentration of a solution prepared by dissolving 225 L of HCl(g) at 37°C and 89.6 kPa in 5.25 L of water?


A) 1.49 M
B) 1.66 M
C) 7.82 M
D) 12.5 M
E) 16.6 M

F) None of the above
G) C) and D)

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A 0.850-mole sample of nitrous oxide, a gas used as an anesthetic by dentists, has a volume of 20.46 L at 123°C and 1.35 atm. What would be its volume at 468°C and 1.35 atm?


A) 5.38 L
B) 10.9 L
C) 19.0 L
D) 38.3 L
E) 77.9 L

F) A) and C)
G) A) and B)

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At moderate pressures (~ 200 atm) , the measured pressure exerted by CO2 gas is less than that predicted by the ideal gas equation. This is mainly because


A) such high pressures cannot be accurately measured.
B) CO 2 will condense to a liquid at 200 atm pressure.
C) gas phase collisions prevent CO 2 molecules from colliding with the walls of the container.
D) of attractive intermolecular forces between CO 2 molecules.
E) the volume occupied by the CO 2 molecules themselves becomes significant.

F) B) and C)
G) A) and E)

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The temperature of the carbon dioxide atmosphere near the surface of Venus is 475°C. Calculate the average kinetic energy per mole of carbon dioxide molecules on Venus.


A) 2520 J/mol
B) 4150 J/mol
C) 5920 J/mol
D) 9330 J/mol
E) 5920 kJ/mol

F) A) and E)
G) A) and D)

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