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In combustion analysis, the carbon and hydrogen contents of a substance are determined from the CO2 and H2O, respectively, which are collected in the absorbers.

A) True
B) False

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In combustion analysis, the oxygen content of a substance is equal to the total oxygen in the CO2 and H2O collected in the absorbers.

A) True
B) False

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Calculate the molar mass of (NH4) 3AsO4.


A) 417.80 g/mol
B) 193.03 g/mol
C) 165.02 g/mol
D) 156.96 g/mol
E) 108.96 g/mol

F) None of the above
G) A) and B)

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Hydroxylamine nitrate contains 29.17 mass % N, 4.20 mass % H, and 66.63 mass O. If its molar mass is between 94 and 98 g/mol, what is its molecular formula?


A) NH2O5
B) N2H4O4
C) N3H3O3
D) N4H8O2
E) N2H2O4

F) D) and E)
G) A) and C)

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Magnesium (used in the manufacture of light alloys) reacts with iron(III) chloride to form magnesium chloride and iron. 3Mg(s) + 2FeCl3(s) → 3MgCl2(s) + 2Fe(s) A mixture of 41.0 g of magnesium ( Magnesium (used in the manufacture of light alloys)  reacts with iron(III)  chloride to form magnesium chloride and iron. 3Mg(s)  + 2FeCl<sub>3</sub>(s)  → 3MgCl<sub>2</sub>(s)  + 2Fe(s)  A mixture of 41.0 g of magnesium (   = 24.31 g/mol)  and 175 g of iron(III)  chloride (   = 162.2 g/mol)  is allowed to react. Identify the limiting reactant and determine the mass of the excess reactant present in the vessel when the reaction is complete. A)  Limiting reactant is Mg; 67 g of FeCl<sub>3</sub> remain. B)  Limiting reactant is Mg; 134 g of FeCl<sub>3</sub> remain. C)  Limiting reactant is Mg; 104 g of FeCl<sub>3</sub> remain. D)  Limiting reactant is FeCl<sub>3</sub>; 2 g of Mg remain. E)  Limiting reactant is FeCl<sub>3</sub>; 87 g of Mg remain. = 24.31 g/mol) and 175 g of iron(III) chloride ( Magnesium (used in the manufacture of light alloys)  reacts with iron(III)  chloride to form magnesium chloride and iron. 3Mg(s)  + 2FeCl<sub>3</sub>(s)  → 3MgCl<sub>2</sub>(s)  + 2Fe(s)  A mixture of 41.0 g of magnesium (   = 24.31 g/mol)  and 175 g of iron(III)  chloride (   = 162.2 g/mol)  is allowed to react. Identify the limiting reactant and determine the mass of the excess reactant present in the vessel when the reaction is complete. A)  Limiting reactant is Mg; 67 g of FeCl<sub>3</sub> remain. B)  Limiting reactant is Mg; 134 g of FeCl<sub>3</sub> remain. C)  Limiting reactant is Mg; 104 g of FeCl<sub>3</sub> remain. D)  Limiting reactant is FeCl<sub>3</sub>; 2 g of Mg remain. E)  Limiting reactant is FeCl<sub>3</sub>; 87 g of Mg remain. = 162.2 g/mol) is allowed to react. Identify the limiting reactant and determine the mass of the excess reactant present in the vessel when the reaction is complete.


A) Limiting reactant is Mg; 67 g of FeCl3 remain.
B) Limiting reactant is Mg; 134 g of FeCl3 remain.
C) Limiting reactant is Mg; 104 g of FeCl3 remain.
D) Limiting reactant is FeCl3; 2 g of Mg remain.
E) Limiting reactant is FeCl3; 87 g of Mg remain.

F) A) and C)
G) A) and D)

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Methanol (CH4O) is converted to bromomethane (CH3Br) as follows: CH4O + HBr → CH3Br + H2O If 12.23 g of bromomethane are produced when 5.00 g of methanol is reacted with excess HBr, what is the percentage yield?


A) 40.9%
B) 82.6%
C) 100%
D) 121%
E) 245%

F) B) and E)
G) A) and D)

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Magnesium reacts with iron(III) chloride to form magnesium chloride (which can be used in fireproofing wood and in disinfectants) and iron. 3Mg(s) + 2FeCl3(s) → 3MgCl2(s) + 2Fe(s) A mixture of 41.0 g of magnesium ( Magnesium reacts with iron(III)  chloride to form magnesium chloride (which can be used in fireproofing wood and in disinfectants)  and iron. 3Mg(s)  + 2FeCl<sub>3</sub>(s)  → 3MgCl<sub>2</sub>(s)  + 2Fe(s)  A mixture of 41.0 g of magnesium (   = 24.31 g/mol)  and 175 g of iron(III)  chloride (   = 162.2 g/mol)  is allowed to react. What mass of magnesium chloride = 95.21 g/mol)  is formed? A)  68.5 g MgCl<sub>2</sub> B)  77.0 g MgCl<sub>2</sub> C)  71.4 g MgCl<sub>2</sub> D)  107 g MgCl<sub>2</sub> E)  154 g MgCl<sub>2</sub> = 24.31 g/mol) and 175 g of iron(III) chloride ( Magnesium reacts with iron(III)  chloride to form magnesium chloride (which can be used in fireproofing wood and in disinfectants)  and iron. 3Mg(s)  + 2FeCl<sub>3</sub>(s)  → 3MgCl<sub>2</sub>(s)  + 2Fe(s)  A mixture of 41.0 g of magnesium (   = 24.31 g/mol)  and 175 g of iron(III)  chloride (   = 162.2 g/mol)  is allowed to react. What mass of magnesium chloride = 95.21 g/mol)  is formed? A)  68.5 g MgCl<sub>2</sub> B)  77.0 g MgCl<sub>2</sub> C)  71.4 g MgCl<sub>2</sub> D)  107 g MgCl<sub>2</sub> E)  154 g MgCl<sub>2</sub> = 162.2 g/mol) is allowed to react. What mass of magnesium chloride = 95.21 g/mol) is formed?


A) 68.5 g MgCl2
B) 77.0 g MgCl2
C) 71.4 g MgCl2
D) 107 g MgCl2
E) 154 g MgCl2

F) A) and C)
G) B) and D)

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Sulfur trioxide can react with atmospheric water vapor to form sulfuric acid that falls as acid rain. Calculate the mass in grams of 3.65 × 1020 molecules of SO3.


A) 6.06 × 10-4 g
B) 2.91 × 10-2 g
C) 4.85 × 10-2 g
D) 20.6 g
E) 1650 g

F) B) and E)
G) A) and D)

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C

Terephthalic acid, used in the production of polyester fibers and films, is composed of carbon, hydrogen, and oxygen. When 0.6943 g of terephthalic acid was subjected to combustion analysis it produced 1.471 g CO2 and 0.226 g H2O. What is its empirical formula?


A) C2H3O4
B) C3H4O2
C) C4H3O2
D) C5H12O4
E) C2H2O

F) B) and D)
G) All of the above

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A compound containing chromium and silicon contains 73.52 mass percent chromium. Determine its empirical formula.


A) CrSi3
B) Cr2Si3
C) Cr3Si
D) Cr3Si2
E) Cr2S

F) C) and E)
G) A) and D)

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Constitutional (structural) isomers have the same empirical formula but different molecular formulas.

A) True
B) False

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How many atoms are in a drop of mercury that has a diameter of 1.0 mm? (Volume of a sphere is 4πr3/3; density of mercury = 13.6 g/cm3)


A) 2.1 × 1019
B) 1.7 × 1020
C) 2.1 × 1022
D) 1.7 × 1023
E) None of these choices are correct.

F) A) and B)
G) A) and C)

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A

Aluminum will react with bromine to form aluminum bromide (used as an acid catalyst in organic synthesis) . Al(s) + Br2(l) → Al2Br6(s) [unbalanced] How many moles of Al are needed to form 2.43 mol of Al2Br6?


A) 7.29 mol
B) 4.86 mol
C) 2.43 mol
D) 1.62 mol
E) 1.22 mol

F) A) and C)
G) A) and B)

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Alkanes are compounds of carbon and hydrogen with the general formula CnH2n+2. An alkane component of gasoline has a molar mass of between 125 and 130 g/mol. What is the value of n for this alkane?


A) 4
B) 9
C) 10
D) 13
E) 14

F) A) and B)
G) B) and C)

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B

Calculate the molar mass of rubidium carbonate, Rb2CO3.


A) 340.43 g/mol
B) 255.00 g/mol
C) 230.94 g/mol
D) 145.47 g/mol
E) 113.48 g/mol

F) B) and E)
G) A) and B)

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The number of hydrogen atoms in 0.050 mol of C3H8O3 is


A) 3.0 × 1022 H atoms.
B) 1.2 × 1023 H atoms.
C) 2.4 × 1023 H atoms.
D) 4.8 × 1023 H atoms.
E) None of these choices are correct.

F) A) and D)
G) A) and B)

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Terephthalic acid, used in the production of polyester fibers and films, is composed of carbon, hydrogen, and oxygen. When 0.6943 g of terephthalic acid was subjected to combustion analysis it produced 1.471 g CO2 and 0.226 g H2O. If its molar mass is between 158 and 167 g/mol, what is its molecular formula?


A) C4H6O7
B) C6H8O5
C) C7H12O4
D) C4H3O2
E) C8H6O4

F) C) and D)
G) A) and B)

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Balance the following equation: Ca3(PO4) 2(s) + SiO2(s) + C(s) → CaSiO3(s) + CO(g) + P4(s)


A) Ca3(PO4) 2(s) + 3SiO2(s) + 8C(s) → 3CaSiO3(s) + 8CO(g) + P4(s)
B) Ca3(PO4) 2(s) + 3SiO2(s) + 14C(s) → 3CaSiO3(s) + 14CO(g) + P4(s)
C) Ca3(PO4) 2(s) + 3SiO2(s) + 8C(s) → 3CaSiO3(s) + 8CO(g) + 2P4(s)
D) 2Ca3(PO4) 2(s) + 6SiO2(s) + 10C(s) → 6CaSiO3(s) + 10CO(g) + P4(s)
E) 2Ca3(PO4) 2(s) + 6SiO2(s) + 10C(s) → 6CaSiO3(s) + 10CO(g) + 4P4(s)

F) A) and C)
G) C) and D)

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Aluminum sulfate, Al2(SO4) 3, is used in tanning leather, purifying water, and manufacture of antiperspirants. Calculate its molar mass.


A) 450.06 g/mol
B) 342.15 g/mol
C) 315.15 g/mol
D) 278.02 g/mol
E) 74.98 g/mol

F) C) and D)
G) D) and E)

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What is the mass in grams of 0.250 mol of the common antacid calcium carbonate?


A) 4.00 × 102 g
B) 25.0 g
C) 17.0 g
D) 4.00 × 10-2 g
E) 2.50 × 10-3 g

F) C) and D)
G) A) and E)

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