A) The bond angle of the carbonyl is larger than the bond angle of the alkene.
B) The electronegative oxygen of the C=O group makes this bond polar.
C) The bond of the C=C is longer that the bond of the C=O.
D) There is more steric crowding in the carbonyl than in the alkene.
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) NaBH4/CH3OH
B) H2,Pd-C
C) LiAlH4 then H2O
D) MeMgBr then H2O
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) NaBH4
B) LiAlH(OtBu) 3
C) LiAlH4
D) FeCl3
Correct Answer
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Multiple Choice
A) Both reagents contain polar metal-hydrogen bonds.The polarity of the B-H bond is greater than the polarity of the Al-H bond,so LiAlH4 is the stronger reducing agent.
B) Both reagents contain polar metal-hydrogen bonds.The polarity of the B-H bond is greater than the polarity of the Al-H bond,so LiAlH4 is the weaker reducing agent.
C) Both reagents contain polar metal-hydrogen bonds.The polarity of the B-H bond is less than the polarity of the Al-H bond,so LiAlH4 is the stronger reducing agent.
D) Both reagents contain polar metal-hydrogen bonds.The polarity of the B-H bond is less than the polarity of the Al-H bond,so LiAlH4 is the weaker reducing agent.
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) Nucleophilic attack followed by protonation
B) Nucleophilic attack followed by deprotonation
C) Nucleophilic attack followed by substitution
D) Nucleophilic attack followed by elimination
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) Ketones are more sterically hindered
B) Ketones are less electron deficient due to donation from the two alkyl groups
C) The statement is false; ketones are more reactive than aldehydes
D) Both Ketones are more sterically hindered and Ketones are less electron deficient due to donation from the two alkyl groups
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) NaBH4
B) LiAlH(OtBu) 3
C) LiAlH4
D) FeCl3
Correct Answer
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Multiple Choice
A) III > I > IV > II
B) II > IV > I > III
C) IV > II > III > I
D) II > IV > III > I
Correct Answer
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Multiple Choice
A) I
B) II
C) III
D) IV
Correct Answer
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Multiple Choice
A) PhMgBr then H2O
B) Benzene,AlCl3
C) Ph2CuLi then H2O
D) PhLi then H2O
Correct Answer
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